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Tiglic aldehyde was used in the concise total synthesis of 7-demethylpiericidin A11. It was used as starting reagent during the synthesis of alkyl-branched tetraene hydrocarbons, pheromone component for dried fruit beetle.
Elena Jiménez.; Beatriz Lanza.; María Antiñolo.; José Albaladejo. Influence of temperature on the chemical removal of 3-methylbutanal, trans-2-methyl-2-butenal, and 3-methyl-2-butenal by OH radicals in the troposphere. Atmospheric Environment. 2009, 43, (26), 4043-4049.
Daryl D. Rowan.; Heather P. Lane.; John M. Allen.; Simon Fielder.; Martin B. Hunt. Biosynthesis of 2-Methylbutyl, 2-Methyl-2-butenyl, and 2-Methylbutanoate Esters in Red Delicious and Granny Smith Apples Using Deuterium-Labeled Substrates. J. Agric. Food Chem. 1996, 44, (10), 3276-3285.
Hazard Statements: H225-H315-H319-H335
Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.