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2052-49-5 - Tetra-n-butylammonium hydroxide, 1.0M in methanol - L08164 - Alfa Aesar

L08164 Tetra-n-butylammonium hydroxide, 1.0M in methanol

CAS Number
2052-49-5
Synonyms

Size Price ($) Quantity Availability
25ml 21.50
100ml 49.10
500ml 189.00
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Tetra-n-butylammonium hydroxide, 1.0M in methanol

MDL
MFCD00009425
EINECS
218-147-6

Chemical Properties

Formula
[CH3(CH2)3]4NOH
Formula Weight
259.48
Flash Point
11°(51°F)
Density
0.830
Refractive Index
1.3825
Sensitivity
Air Sensitive & Hygroscopic
Solubility
Miscible with organic solvents.

Applications

Tetra-n-butylammonium hydroxide, 1.0M in methanol is used as a strong base in organic chemistry. It is utilized under phase-transfer conditions to effect alkylation and deprotonation.

Notes

Air sensitive and hygroscopic. Incompatible with strong acids and corrodes metal.

Literature References

Li, S. H.; Li, Z. J.; Nakagawa, T.; Ryan, J. W.; Matsuo, Y.; Gao, X. Approach to High Open-Circuit Voltage in Organic Solar Cells Utilizing a Structural Change of the Oxazolino-C70 Derivative. Chem. Eur. J. 2015, 21 (5), 1894-1899.

Ou, Z.; Meng, D.; Yuan, M.; Huang, W.; Fang, Y.; Kadish, K. M. Deprotonation Reactions and Electrochemistry of Substituted Open-Chain Pentapyrroles and Sapphyrins in Basic Nonaqueous Media. J. Phys. Chem. B 2013, 117 (43), 13646-13657.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H311-H331-H314-H318-H370

Highly flammable liquid and vapour. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Causes damage to organs.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3571228
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2923.90
TSCA
Yes
RTECS
BS5425000

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