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96-29-7 - 2-Butanone oxime, 99% - Ethyl methyl ketoxime - Methyl ethyl ketoxime - L08196 - Alfa Aesar

L08196 2-Butanone oxime, 99%

CAS Number
96-29-7
Synonyms
Ethyl methyl ketoxime
Methyl ethyl ketoxime

Size Price ($) Quantity Availability
100ml 19.50
500ml 37.50
1000ml 60.30
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2-Butanone oxime, 99%

MDL
MFCD00013935
EINECS
202-496-6

Chemical Properties

Formula
C4H9NO
Formula Weight
87.12
Melting point
-30°
Boiling Point
152-153°
Flash Point
62°(144°F)
Density
0.921
Refractive Index
1.4430
Solubility
Soluble in water at 20°C 114 g/L. Soluble in most organic solvents .

Applications

2-Butanone oxime was employed as reagent and solvent in the syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes. It was also used in the synthesis of novel acetaldiimine cobalt complex, [CoI2{((CH3CH2)(CH3)C=NO)2C(CH3)2}]. Methyl ethyl ketoxime is used primarily as an antiskinning agent in alkyd coating resins

Notes

Store away from acids and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep ignition sources away.

Literature References

Maximilian N Kopylovich, et al. Single-pot template transformations of cyanopyridines on a Pd(II) centre: syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes and their catalytic activity for microwave-assisted Suzuki-Miyaura and Heck reactions. Dalton Trans.,2009,163074-3084.

Hierso J-C, et al. Cobalt-Assisted Condensation of 2-Butanone Oxime and Acetone: Synthesis and X-ray Structure of the Novel Acetaldiimine Complex [CoI2 {((CH3CH2)(CH3) C= NO) 2C (CH3) 2}].Eur. J. Inorg. Chem.,2000,2000(12), 2459-62.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H312-H318-H317-H351

Combustible liquid. Harmful in contact with skin. Causes serious eye damage. May cause an allergic skin reaction. Suspected of causing cancer.

Precautionary Statements: P260-P201-P280a-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1698241
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
EL9275000

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