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5780-07-4 - 5-Methoxypiperonal, 97% - 7-Methoxy-1,3-benzodioxole-5-carboxaldehyde - 3-Methoxy-4,5-(methylenedioxy)benzaldehyde - L08213 - Alfa Aesar

L08213 5-Methoxypiperonal, 97%

CAS Number
5780-07-4
Synonyms
7-Methoxy-1,3-benzodioxole-5-carboxaldehyde
3-Methoxy-4,5-(methylenedioxy)benzaldehyde

Size Price ($) Quantity Availability
1g 42.10
5g 134.00
25g 505.00
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5-Methoxypiperonal, 97%

MDL
MFCD00016900
EINECS
227-304-8

Chemical Properties

Formula
C9H8O4
Formula Weight
180.16
Melting point
126-132°
Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Applications

5-Methoxypiperonal is used in the synthesis of oxazole combretastatin A-4 analogs showing anti-tumor activity. It is also used in the synthesis of endothelin-A antagonist ABT-546, and further in the synthesis of antidepressant rolipram.

Notes

Air Sensitive. Incompatible with air, oxidizing agents. Store under dry inert gas. Store away from air.

Literature References

David M. Barnes; Jianguo Ji; Michael G. Fickes; Michael A. Fitzgerald; Steven A. King; Howard E. Morton; Frederick A. Plagge; Margo Preskill; Seble H. Wagaw; Steven J. Wittenberger and Ji Zhang. Development of a Catalytic Enantioselective Conjugate Addition of 1,3-Dicarbonyl Compounds to Nitroalkenes for the Synthesis of Endothelin-A Antagonist ABT-546. Scope, Mechanism, and Further Application to the Synthesis of the Antidepressant Rolipram. J. Am. Chem. Soc. 2002, 124 (44), 13097-13105.

Other References

Beilstein
384077
Harmonized Tariff Code
2912.49
TSCA
Yes

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