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L08269 Lithium aluminum di-n-butylamide, 0.16M soln. in 1,2-dimethoxyethane

CAS Number
15405-86-4
Synonyms

Stock No. Size Price ($) Quantity Availability
L08269-AE 100ml 137.00
L08269-AP 500ml 514.00
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Lithium aluminum di-n-butylamide, 0.16M soln. in 1,2-dimethoxyethane

MDL
MFCD00051918

Chemical Properties

Formula
C32H72AlLiN4
Formula Weight
546.87
Melting point
-54°
Density
0.860
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Air Sensitive. Store under Argon.

Applications

Lithium aluminum di-n-butylamide is used as a reagent for the determination of hydroxyl groups in silanols.

Notes

Air, heat and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, air, heat and water.

Literature References

Reagent for determination of silanols: Anal. Chem., 39, 1623 (1967); Analysis of Silicones, A. L. Smith, Ed., Wiley, N.Y. (1974).

Kozlova, S. A.; Kirik, S. D. Post-synthetic activation of silanol covering in the mesostructured silicate materials ???-41 and SBA-15. Microporous Mesoporous Mater. 2010, 133, (1), 124-133.

Kosonen, J. P.; Ruohonen, J. K. A Simple Karl Fischer Titration Procedure for Determination of Total Hydroxyl Content in Silanol-Terminated Polvsiloxanes. Int. J. Polym. Anal. Charact. 1998, 4 (4), 283-293.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H332-H360FD

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May damage fertility. Suspected of damaging the unborn child. May damage fertility. May damage the unborn child.

Precautionary Statements: P201-P202-P210-P233-P240-P241-P242-P243-P261-P264b-P271-P280i-P281-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P332+P313-P337+P313-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If skin irritation occurs: If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2921.19
TSCA
No

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