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L08943 2,3-Dichloro-1-propene, 98%

CAS Number
78-88-6
Synonyms

Stock No. Size Price ($) Quantity Availability
L08943-18 50g 68.60
L08943-30 250g 249.00
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2,3-Dichloro-1-propene, 98%

MDL
MFCD00000943
EINECS
201-153-8

Chemical Properties

Formula
C3H4Cl2
Formula Weight
110.97
Melting point
-83°
Boiling Point
93-96°
Flash Point
10°(50°F)
Density
1.209
Refractive Index
1.4620
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (2g/L).

Applications

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

T Neudecker and D Henschler. Mutagenicity of chloroolefins in the Salmonella/mammalian microsome test. III. Metabolic activation of the allylic chloropropenes allyl chloride, 1,3-dichloropropene, 2,3-dichloro-1-propene, 1,2,3-trichloropropene, 1,1,2,3-tetrachloro-2-propene and hexachloropropene by S9 mix via two different metabolic pathways. Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis,1986, 107 (1-2), 1-9.

Roland P H Schmitz et. al. Evidence for a radical mechanism of the dechlorination of chlorinated propenes mediated by the tetrachloroethene reductive dehalogenase of Sulfurospirillum muftivorans. Environmental Science & Technology. 2007, 41 (21), 7370-7375.

Reductive elimination with Zn powder gives allene free from methylacetylene: Org. Synth. Coll., 5, 22 (1973).

Electron-acceptor, with concomitant reduction to allene, in a high-yield coupling of aryl Grignard reagents to symmetrical biaryls: Tetrahedron Lett., 29, 1293 (1988):

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H312-H315-H318-H332-H335-H340

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye damage. Harmful if inhaled. May cause respiratory irritation. May cause genetic defects.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P281-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P312-P330-P332+P313-P363-P370+P378q-P50

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam

Other References

Beilstein
1361491
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.29
TSCA
Yes
RTECS
UC8400000

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