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78-88-6 - 2,3-Dichloro-1-propene, 98% - L08943 - Alfa Aesar

L08943 2,3-Dichloro-1-propene, 98%

CAS Number
78-88-6
Synonyms

Size Price ($) Quantity Availability
10g 23.40
50g 66.10
250g 244.00
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2,3-Dichloro-1-propene, 98%

MDL
MFCD00000943
EINECS
201-153-8

Chemical Properties

Formula
C3H4Cl2
Formula Weight
110.97
Melting point
-83°
Boiling Point
93-96°
Flash Point
10°(50°F)
Density
1.209
Refractive Index
1.4620
Solubility
Soluble in water (2g/L).

Applications

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

T Neudecker and D Henschler. Mutagenicity of chloroolefins in the Salmonella/mammalian microsome test. III. Metabolic activation of the allylic chloropropenes allyl chloride, 1,3-dichloropropene, 2,3-dichloro-1-propene, 1,2,3-trichloropropene, 1,1,2,3-tetrachloro-2-propene and hexachloropropene by S9 mix via two different metabolic pathways. Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis,1986, 107 (1-2), 1-9.

Roland P H Schmitz et. al. Evidence for a radical mechanism of the dechlorination of chlorinated propenes mediated by the tetrachloroethene reductive dehalogenase of Sulfurospirillum muftivorans. Environmental Science & Technology. 2007, 41 (21), 7370-7375.

Reductive elimination with Zn powder gives allene free from methylacetylene: Org. Synth. Coll., 5, 22 (1973).

Electron-acceptor, with concomitant reduction to allene, in a high-yield coupling of aryl Grignard reagents to symmetrical biaryls: Tetrahedron Lett., 29, 1293 (1988):

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H318-H315-H341-H302-H312-H332-H335-H412

Highly flammable liquid and vapour. Causes serious eye damage. Causes skin irritation. Suspected of causing genetic defects. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. May cause respiratory irritation. Harmful to aquatic life with long lasting effects.

Precautionary Statements: P210-P201-P261-P273-P280-P281-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1361491
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.29
TSCA
Yes
RTECS
UC8400000

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