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759-24-0 - Diethyl tert-butylmalonate, 97% - tert-Butylmalonic acid diethyl ester - L09131 - Alfa Aesar

L09131 Diethyl tert-butylmalonate, 97%

CAS Number
759-24-0
Synonyms
tert-Butylmalonic acid diethyl ester

Size Price ($) Quantity Availability
1g 30.40
5g 96.90
25g 392.00
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Diethyl tert-butylmalonate, 97%

MDL
MFCD00009152
EINECS
212-067-5

Chemical Properties

Formula
C11H20O4
Formula Weight
216.28
Boiling Point
102-104°/11mm
Flash Point
90°(194°F)
Density
0.978
Refractive Index
1.4250
Solubility
Immiscible with water.

Applications

Diethyl tert-butylmalonate is used in the preparation of enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Patel, N. C.; Schwarz, J. B.; Islam, K.; Miller, W.; Tran, T. P.; Wei, Y. Improved Synthesis of gamma-Lactones from Cyclopropyl Cyanoesters. Synth. Commun. 2011, 41 (15), 2209-2215.

Huang, J. Y.; Zhuang, J. M.; Zou, Y. S. Substituent effects of accelerator on nitroxide-mediated radical polymerization. Macromol. Res. 2011, 19 (8), 757-763.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1781709
Harmonized Tariff Code
2917.19
TSCA
No

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