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Through the stereo displacement of (S)-(-)-2-Chloropropionic acid PPAR Agonist can be synthesized via asymmetric hydrogenation of a cinnamic acid derivative.
Ioannis N. Houpis.; Lawrence E. Patterson.; Charles A. Alt.; John R. Rizzo.; Tony Y. Zhang.; Michael Haurez. Synthesis of PPAR Agonist via Asymmetric Hydrogenation of a Cinnamic Acid Derivative and Stereospecific Displacement of (S)-2-Chloropropionic Acid.Org. Lett. 2005, 7 (10),1947-1950 .
Atsushi Kurata.; Tatsuo Kurihara.; Harumi Kamachi.; Nobuyoshi Esaki. Asymmetric reduction of 2-chloroacrylic acid to (S)-2-chloropropionic acid by a novel reductase from Burkholderia sp. WSTetrahedron: Asymmetry. 2004, 15 (18),2837-2839 .
Hazard Statements: H302-H312-H314-H318
Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.