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Vinyl chloroacetate was used to study the effect of the electron-withdrawing groups on the ligand in a series of bis(acetylacetonate)cobalt(II) derivatives. It is used for the enzyme-catalyzed, regioselective acylation of carbohydrates.
Martin Hauser. The Reaction of Vinyl Chloroacetate with Some Nucleophilic Reagents. J. Org. Chem. 1962, 27 (1),43-46 .
Hiromu Kaneyoshi.; Krzysztof Matyjaszewski. Radical (Co)polymerization of Vinyl Chloroacetate and N-Vinylpyrrolidone Mediated by Bis(acetylacetonate)cobalt Derivatives.Macromolecules. 2006, 39 (8),2757-2763 .
Hazard Statements: H226-H300-H310-H330-H314-H318
Flammable liquid and vapour. Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P301+P310a-P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a
IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.