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2549-51-1 - Vinyl chloroacetate, 99%, stab. with 4-methoxyphenol - Chloroacetic acid vinyl ester - L09446 - Alfa Aesar

L09446 Vinyl chloroacetate, 99%, stab. with 4-methoxyphenol

CAS Number
2549-51-1
Synonyms
Chloroacetic acid vinyl ester

Size Price ($) Quantity Availability
10g 34.90
50g 122.00
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Vinyl chloroacetate, 99%, stab. with 4-methoxyphenol

MDL
MFCD00045275
EINECS
219-834-3

Chemical Properties

Formula
ClCH2CO2CH=CH2
Formula Weight
120.54
Boiling Point
136°
Flash Point
51°(123°F)
Density
1.190
Refractive Index
1.4435
Solubility
Difficult to mix in water.

Applications

Vinyl chloroacetate was used to study the effect of the electron-withdrawing groups on the ligand in a series of bis(acetylacetonate)cobalt(II) derivatives. It is used for the enzyme-catalyzed, regioselective acylation of carbohydrates.

Notes

Store at room temperature. Incompatible with strong oxidizing agents.

Literature References

Martin Hauser. The Reaction of Vinyl Chloroacetate with Some Nucleophilic Reagents. J. Org. Chem. 1962, 27 (1),43-46 .

Hiromu Kaneyoshi.; Krzysztof Matyjaszewski. Radical (Co)polymerization of Vinyl Chloroacetate and N-Vinylpyrrolidone Mediated by Bis(acetylacetonate)cobalt Derivatives.Macromolecules. 2006, 39 (8),2757-2763 .

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H300-H310-H330-H314-H318

Flammable liquid and vapour. Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P301+P310a-P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a

IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1741679
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2915.39
TSCA
Yes

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