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L09558 (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+%

CAS Number
35132-20-8
Synonyms
(1R,2R)-(+)-1,2-Diamino-1,2-diphenylethane
(1R,2R)-(+)-1,2-Diphenylethylenediamine

Stock No. Size Price ($) Quantity Availability
L09558-MD 250mg 21.90
L09558-03 1g 57.10
L09558-06 5g 167.00
L09558-14 25g 590.00
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(1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+%

MDL
MFCD00082769

Chemical Properties

Formula
C14H16N2
Formula Weight
212.30
Melting point
80-84°
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Nitrogen.
Solubility
Insoluble in water.

Applications

(1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine is used as chiral solvation agent for determination of enantiomeric excess of chiral acids by NMR. It is used in various catalyst systems for asymmetric reactions.

Notes

Air Sensitive. Store away from air. Protect from heat. Store under dry inert gas. Incompatible with heat, air and oxidizing agents.

Literature References

François Touchard; Patrick Gamez; Fabienne Fache; Marc Lemaire. Chiral thiourea as ligand for the asymmetric reduction of prochiral ketones. Chiral thiourea as ligand for the asymmetric reduction of prochiral ketones.Tetrahedron Letters.1997, 38 2275-2278.

Chiral solvation agent for determination of enantiomeric excess of chiral acids by NMR.

In combination with various Lewis acids, forms a number of catalyst systems for asymmetric reactions including Diels-Alder, allylation and aldol reactions: Angew. Chem. Int. Ed., 30, 455 (1991). For use in enantioselective catalytic Diels-Alder reactions, see: J. Am. Chem. Soc., 111, 5493 (1989); Org. Synth. Coll., 9, 67 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2369988
Harmonized Tariff Code
2921.59
TSCA
No

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