L09617 2,3,4,5-Tetramethyl-2-cyclopentenone, cis + trans, 95%
SDS
| Stock No. | Size | Price ($) | Quantity | Availability |
|---|---|---|---|---|
| L09617-06 | 5g | 54.50 |
|
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| L09617-14 | 25g | 197.00 |
|
|
2,3,4,5-Tetramethyl-2-cyclopentenone, cis + trans, 95%
Chemical Properties
Applications
2,3,4,5-Tetramethyl-2-cyclopentenone was used in the synthesis of chiral pre-ligands, (R)-3,3?-bis(tetramethylcyclopentadienyl)-2,2?-bismethoxy-1,1?-bisnaphthalene and (R)-3-tetramethylcyclopentadienyl-2,2?-bismethoxy-1,1?-bisnaphthalene by reacting with (R)-3,3?-dilithium-2,2?-bismethoxy-1,1?-bisnaphthalene.
Notes
Literature References
Eric A. Mintz; Jerome C. Pando; Irene Zervos. Convenient preparation of 1,3-bis(2,3,4,5-tetramethylcyclopentadienyl)propane. 2,3,4,5-Tetramethyl-2-cyclopentenone enolate as a synthetic equivalent for the tetramethylcyclopentadienyl anion.J. Org. Chem.1987, 52 (13), 2948-2950.
Li Wang; Qiaolin Wu; Hao Xu; Ying Mu. Synthesis and structures of (R)-cyclopentadienyl-binaphthoxy titanium(IV) complexes and catalytic properties for olefin polymerization.Dalton Transactions.2012, 41 (24), 7350-7357.
GHS Hazard and Precautionary Statements
Hazard Statements: H227
Combustible liquid.
Precautionary Statements: P210-P280-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant
Other References
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