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L09779 (S)-(+)-Prolinol, 98%

CAS Number
23356-96-9
Synonyms
H-Pro-ol
(S)-(+)-2-Pyrrolidinemethanol

Stock No. Size Price ($) Quantity Availability
L09779-03 1g 28.20
L09779-06 5g 96.40
L09779-14 25g 296.00
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(S)-(+)-Prolinol, 98%

MDL
MFCD00005255
EINECS
245-605-2

Chemical Properties

Formula
C5H11NO
Formula Weight
101.15
Melting point
42-44°
Boiling Point
74-76°/2mm
Flash Point
86°(186°F)
Density
1.025
Refractive Index
1.4853
Storage & Sensitivity
Air Sensitive. Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Fully miscible in water. Soluble in chloroform.

Applications

It is an active pharmaceutical intermediate.

Notes

Store at room temperature. Incompatible with strong oxidizing agents.

Literature References

Shinichi Itsuno.; Koichi Ito.; Akira Hirao.; Seiichi Nakahama. Asymmetric synthesis using chirally modified borohydrides. Part 2. Enantioselective reduction of ketones with polymeric (S)-prolinol-borane reagent.J. Chem. Soc., Perkin Trans. 1. 1984, 2887-2893 .

David Alker.; Kevin J. Doyle.; Laurence M. Harwood.; Andrew McGregor. The direct synthesis of the cyclic sulphamidate of (S)-prolinol: SimultaneousN-protection and activation towards nucleophilic displacement of oxygen.Tetrahedron: Asymmetry. 1990, 1 (12),877-880 .

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
79843
Harmonized Tariff Code
2933.99
TSCA
No

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