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23356-96-9 - (S)-(+)-Prolinol, 98% - H-Pro-ol - (S)-(+)-2-Pyrrolidinemethanol - L09779 - Alfa Aesar

L09779 (S)-(+)-Prolinol, 98%

CAS Number
23356-96-9
Synonyms
H-Pro-ol
(S)-(+)-2-Pyrrolidinemethanol

Size Price ($) Quantity Availability
1g 29.80
5g 95.90
25g 287.00
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(S)-(+)-Prolinol, 98%

MDL
MFCD00005255
EINECS
245-605-2

Chemical Properties

Formula
C5H11NO
Formula Weight
101.15
Melting point
42-44°
Boiling Point
74-76°/2mm
Flash Point
86°(186°F)
Density
1.025
Refractive Index
1.4853
Sensitivity
Air Sensitive & Hygroscopic
Solubility
Fully miscible in water. Soluble in chloroform.

Applications

It is an active pharmaceutical intermediate.

Notes

Store at room temperature. Incompatible with strong oxidizing agents.

Literature References

Shinichi Itsuno.; Koichi Ito.; Akira Hirao.; Seiichi Nakahama. Asymmetric synthesis using chirally modified borohydrides. Part 2. Enantioselective reduction of ketones with polymeric (S)-prolinol-borane reagent.J. Chem. Soc., Perkin Trans. 1. 1984, 2887-2893 .

David Alker.; Kevin J. Doyle.; Laurence M. Harwood.; Andrew McGregor. The direct synthesis of the cyclic sulphamidate of (S)-prolinol: SimultaneousN-protection and activation towards nucleophilic displacement of oxygen.Tetrahedron: Asymmetry. 1990, 1 (12),877-880 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H227

Causes skin irritation. Causes serious eye irritation. Combustible liquid.

Precautionary Statements: P210-P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
79843
Harmonized Tariff Code
2933.79
TSCA
No

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