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L09833 (Aminomethyl)phosphonic acid, 99%

CAS Number
1066-51-9
Synonyms
(Aminomethane)phosphonic acid

Stock No. Size Price ($) Quantity Availability
L09833-MD 250mg 43.40
L09833-03 1g 119.00
L09833-06 5g 435.00
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(Aminomethyl)phosphonic acid, 99%

MDL
MFCD00008105
EINECS
000-000-0

Chemical Properties

Formula
CH6NO3P
Formula Weight
111.04
Melting point
ca 290° dec.
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in water.

Applications

(Aminomethyl)phosphonic acid is used in the preparation of (acetylamino-methyl)-phosphonic acid by reacting with acetic anhydride. Further, it is used in the development of immobilized metal affinity chromatography column based on organic-inorganic hybrid silica monolith.

Notes

Hygroscopic. Incompatible with strong bases and oxidizing agents.

Literature References

For a synthesis of other 1-aminoalkylphosphonates from alkyl phosphonate esters see: Synth. Commun., 21, 1039 (1991).

Arkan, T.; Molnár-Perl, I. The role of derivatization techniques in the analysis of glyphosate and aminomethyl-phosphonic acid by chromatography. Microchem. J. 2015, 121, 99-106.

Ehling, S.; Reddy, T. M. Analysis of Glyphosate and Aminomethylphosphonic Acid in Nutritional Ingredients and Milk by Derivatization with Fluorenylmethyloxycarbonyl Chloride and Liquid Chromatography-Mass Spectrometry. J. Agric. Food Chem. 2015, 63 (48), 10562-10568.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1701219
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2931.39
TSCA
No
RTECS
SZ6526000

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