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1066-51-9 - (Aminomethyl)phosphonic acid, 99% - (Aminomethane)phosphonic acid - L09833 - Alfa Aesar

L09833 (Aminomethyl)phosphonic acid, 99%

CAS Number
1066-51-9
Synonyms
(Aminomethane)phosphonic acid

Size Price ($) Quantity Availability
250mg 41.70
1g 115.00
5g 406.00
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(Aminomethyl)phosphonic acid, 99%

MDL
MFCD00008105
EINECS
000-000-0

Chemical Properties

Formula
CH6NO3P
Formula Weight
111.04
Melting point
ca 290° dec.
Sensitivity
Hygroscopic
Solubility
Soluble in water.

Applications

(Aminomethyl)phosphonic acid is used in the preparation of (acetylamino-methyl)-phosphonic acid by reacting with acetic anhydride. Further, it is used in the development of immobilized metal affinity chromatography column based on organic-inorganic hybrid silica monolith.

Notes

Hygroscopic. Incompatible with strong bases and oxidizing agents.

Literature References

For a synthesis of other 1-aminoalkylphosphonates from alkyl phosphonate esters see: Synth. Commun., 21, 1039 (1991).

Arkan, T.; Molnár-Perl, I. The role of derivatization techniques in the analysis of glyphosate and aminomethyl-phosphonic acid by chromatography. Microchem. J. 2015, 121, 99-106.

Ehling, S.; Reddy, T. M. Analysis of Glyphosate and Aminomethylphosphonic Acid in Nutritional Ingredients and Milk by Derivatization with Fluorenylmethyloxycarbonyl Chloride and Liquid Chromatography-Mass Spectrometry. J. Agric. Food Chem. 2015, 63 (48), 10562-10568.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1701219
Harmonized Tariff Code
2931.39
TSCA
No
RTECS
SZ6526000

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