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75-59-2 - Tetramethylammonium hydroxide, 25% w/w aq. soln. - L09991 - Alfa Aesar

L09991 Tetramethylammonium hydroxide, 25% w/w aq. soln.

CAS Number
75-59-2
Synonyms

Size Price ($) Quantity Availability
100ml 22.00
500ml 68.40
2500ml 258.00
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Tetramethylammonium hydroxide, 25% w/w aq. soln.

MDL
MFCD00008280
EINECS
200-882-9

Chemical Properties

Formula
C4H13NO
Formula Weight
91.15
Boiling Point
ca 102°
Density
1.014
Refractive Index
1.3840
Sensitivity
Air Sensitive
Solubility
Miscible with water.

Applications

Tetramethylammonium hydroxide is used to produce tetramethyl-ammonium azide. It is used as an anisotropic etchant of silicon, as a basic solvent in the development of acidic photoresist in photolithography process, as a surfactant in the synthesis of ferrofluid and as a polarographic reagent. It finds application in the production of organic silicon, where it is used for computer silicon wafer surface brighteners and as a cleaning agent. It is also involved in the purification of some metallic elements.

Notes

Air sensitive. Incompatible with strong oxidizing agents, strong acids, aluminum, alkali metals, strong oxidizing agents, acids, acid chlorides, acid anhydrides and halogens.

Literature References

Whang, L. M.; Hu, T. H.; Liu, P. W. G.; Hung, Y. C.; Fukushima, T.; Wu, Y. J.; Chang, S. H. Molecular analysis of methanogens involved in methanogenic degradation of tetramethylammonium hydroxide in full-scale bioreactors. Appl. Microbiol. Biotechnol. 2015, 99 (3), 1485-1497.

Yin, X.; Li, Z.; Wang, S.; Chu, N.; Yang, J.; Wang, J. Hydrothermal synthesis of hierarchical zeolite T aggregates using tetramethylammonium hydroxide as single template. Microporous Mesoporous Mater. 2015, 201, 247-257.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H314-H318-H370-H372-H373

Fatal if swallowed. Fatal in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260u-P262-P280-P301+P310a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,9224
Beilstein
3558708
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2923.90
TSCA
Yes
RTECS
PA0875000

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