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25597-16-4 - Ethyl 4,4,4-trifluorocrotonate, 98% - 4,4,4-Trifluorocrotonic acid ethyl ester - L10285 - Alfa Aesar

L10285 Ethyl 4,4,4-trifluorocrotonate, 98%

CAS Number
25597-16-4
Synonyms
4,4,4-Trifluorocrotonic acid ethyl ester

Size Price ($) Quantity Availability
1g 31.76
5g 104.80
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Ethyl 4,4,4-trifluorocrotonate, 98%

MDL
MFCD00009903
EINECS
000-000-0

Chemical Properties

Formula
CF3CH=CHCO2CH2CH3
Formula Weight
168.12
Boiling Point
113-115°
Flash Point
25°(77°F)
Density
1.125
Refractive Index
1.3601

Literature References

Shows significantly greater reactivity towards Michael additions than Ethyl­ crotonate, A12529, providing anti-adducts with good selectivity: J. Org. Chem., 60, 4363 (1995):

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/n

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1707262
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2916.19
TSCA
No

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