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814-68-6 - Acryloyl chloride, 96%, stab. with 400ppm phenothiazine - Propenoyl chloride - L10363 - Alfa Aesar

L10363 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine

CAS Number
814-68-6
Synonyms
Propenoyl chloride

Size Price ($) Quantity Availability
10g 37.20
50g 57.90
250g 212.00
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Acryloyl chloride, 96%, stab. with 400ppm phenothiazine

MDL
MFCD00000731
EINECS
212-399-0

Chemical Properties

Formula
C3H3ClO
Formula Weight
90.51
Boiling Point
74-76°
Flash Point
-4°(24°F)
Density
1.114
Refractive Index
1.4350
Sensitivity
Moisture & Light Sensitive
Solubility
Miscible with water.

Applications

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Notes

Moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alcohols, oxidizing agents, strong bases and polymerizing initiators.

Literature References

Warneke, J.; Plaumann, M.; Wang, Z.; Böhler, E.; Kemken, D.; Kelm, S.; Leibfritz, D.; Azov, V. A. New insights into the old reaction between acryloyl chlorides and pyridine. Tetrahedron Lett. 2015, 56 (9), 1124-1127.

Lee, P. W.; Scrape, P. G.; Butler, L. G.; Lee, Y. P. Two HCl-Elimination Channels and Two CO-Formation Channels Detected with Time-Resolved Infrared Emission upon Photolysis of Acryloyl Chloride [CH2CHC(O)Cl] at 193 nm. J. Phys. Chem. A 2015, 119 (28), 7293-7304.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H330-H314-H318

Highly flammable liquid and vapour. Harmful if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
635744
Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2916.19
TSCA
Yes
RTECS
AT7350000

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