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Acetone is a polar, aprotic solvent used in the synthesis and isolation of both organic and inorganic compounds and complexes. It plays a vital role in Jones oxidation. It is utilized for rinsing laboratory glasswares due to its low cost and volatility. It is used in the manufacture of various chemicals such as methyl isobutyl ketone, mesityl oxide, diacetone alcohol, acetic acid, iodoform, bromoform, rayon, photographic films, paint and varnish removers. It is also useful in the synthesis of t-butanesulfinamide, terpenes, thiol-stabilized gold colloids, calixphyrin macrocycles and trispyrazolylborate platinum compounds. It plays an important role in protein crystallization.
Precursor of dimethyldioxirane, by reaction with K monopersulfate, and isolation in solution by low temperature distillation. For details, see: Chem. Ber., 124, 2377 (1991). It is an excellent reagent for rapid, stereospecific epoxidation of alkenes under mild conditions: J. Org. Chem., 50, 2847 (1985); Org. Synth. Coll., 9, 288 (1998). For improved work-up procedure allowing the possibility of more concentrated solutions or the isolation of acetone-free material, see: Tetrahedron Lett., 37, 3585 (1996). For biphasic, environmentally-friendly system (EtOAc-H2 O), see: Org. Process Res. Dev., 6, 407 (2002). Selective oxidation of phosphorus ylides occurs under mild conditions, providing a route to vicinal tricarbonyl derivatives: J. Org. Chem., 60, 8231 (1995). For conversion of ɑ-bromo-ß-dicarbonyls to vicinal tricarbonyls, see: Tetrahedron Lett., 36, 7735 (1995). For formation of singlet oxygen by deoxygenation of heteroaromatic N-oxides, e.g. 4-diethylaminopyridine N-oxide, see: J. Chem. Soc., Chem. Commun., 1831 (1995). For reviews of dioxiranes, see: Acc. Chem. Res., 22, 205 (1989); Chem. Rev., 89, 1187 (1989).
Navarro, R. M.; Guil-Lopez, R.; Ismail, A. A.; Al-Sayari, S. A.; Fierro, J. L. G. Ni-and PtNi-catalysts supported on Al2O3 for acetone steam reforming: Effect of the modification of support with Ce, La and Mg. Catal. Today 2015, 242, 60-70.
Quesada, J.; Faba, L.; Díaz, E.; Bennici, S.; Auroux, A.; Ordóñez, S. Role of surface intermediates in the deactivation of Mg Zr mixed oxides in acetone self-condensation: A combined DRIFT and ex situ characterization approach. J. Catal. 2015, 329, 1-9.
Hazard Statements: H225-H319-H336
Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness.
Precautionary Statements: P260-P201-P280a-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.