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67-64-1 - Acetone, 99+% - L10407 - Alfa Aesar

L10407 Acetone, 99+%

CAS Number
67-64-1
Synonyms

Size Price ($) Quantity Availability
1000ml 21.22
2500ml 43.67
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Acetone, 99+%

MDL
MFCD00008765
EINECS
200-662-2

Chemical Properties

Formula
C3H6O
Formula Weight
58.08
Melting point
-94°
Boiling Point
56°
Flash Point
-17°(1°F)
Density
0.791
Refractive Index
1.3590
Solubility
Miscible with water, benzene, alcohol, dimethylformamide, ether, chloroform and most oils.

Applications

Acetone is a polar, aprotic solvent used in the synthesis and isolation of both organic and inorganic compounds and complexes. It plays a vital role in Jones oxidation. It is utilized for rinsing laboratory glasswares due to its low cost and volatility. It is used in the manufacture of various chemicals such as methyl isobutyl ketone, mesityl oxide, diacetone alcohol, acetic acid, iodoform, bromoform, rayon, photographic films, paint and varnish removers. It is also useful in the synthesis of t-butanesulfinamide, terpenes, thiol-stabilized gold colloids, calixphyrin macrocycles and trispyrazolylborate platinum compounds. It plays an important role in protein crystallization.

Notes

Incompatible with bases, oxidizing agents and reducing agents.

Literature References

Precursor of dimethyldioxirane, by reaction with K monopersulfate, and isolation in solution by low temperature distillation. For details, see: Chem. Ber., 124, 2377 (1991). It is an excellent reagent for rapid, stereospecific epoxidation of alkenes under mild conditions: J. Org. Chem., 50, 2847 (1985); Org. Synth. Coll., 9, 288 (1998). For improved work-up procedure allowing the possibility of more concentrated solutions or the isolation of acetone-free material, see: Tetrahedron Lett., 37, 3585 (1996). For biphasic, environmentally-friendly system (EtOAc-H2 O), see: Org. Process Res. Dev., 6, 407 (2002). Selective oxidation of phosphorus ylides occurs under mild conditions, providing a route to vicinal tricarbonyl derivatives: J. Org. Chem., 60, 8231 (1995). For conversion of ɑ-bromo-ß-dicarbonyls to vicinal tricarbonyls, see: Tetrahedron Lett., 36, 7735 (1995). For formation of singlet oxygen by deoxygenation of heteroaromatic N-oxides, e.g. 4-diethylaminopyridine N-oxide, see: J. Chem. Soc., Chem. Commun., 1831 (1995). For reviews of dioxiranes, see: Acc. Chem. Res., 22, 205 (1989); Chem. Rev., 89, 1187 (1989).

Navarro, R. M.; Guil-Lopez, R.; Ismail, A. A.; Al-Sayari, S. A.; Fierro, J. L. G. Ni-and PtNi-catalysts supported on Al2O3 for acetone steam reforming: Effect of the modification of support with Ce, La and Mg. Catal. Today 2015, 242, 60-70.

Quesada, J.; Faba, L.; Díaz, E.; Bennici, S.; Auroux, A.; Ordóñez, S. Role of surface intermediates in the deactivation of Mg Zr mixed oxides in acetone self-condensation: A combined DRIFT and ex situ characterization approach. J. Catal. 2015, 329, 1-9.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H319-H336

Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness.

Precautionary Statements: P210-P261-P280-P240-P241-P303+P361+P353-P305+P351+P338-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,66
Beilstein
635680
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2914.11
TSCA
Yes
RTECS
AL3150000

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