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Ethyl 4-isocyanatobenzoate was used in the preparation of cellulose carbamate and ester derivatives. It was also used in the preparation of ethyl 4-(3-(4-oxo-6-tridecyl-1,4-dihydropyrimidin-2-yl)ureido)benzoate2 and ethyl 4-(2-oxocyclohexanecarboxamido)benzoate.
Williamson SL,; McCormick CL. Cellulose derivatives synthesized via isocyanate and activated ester pathways in homogeneous solutions of lithium chloride/N, N-dimethylacetamide.. J. Macromol. Sci., Pure Appl. Chem. 1998 , 35 (12), 1915-27.
Pellizzaro ML, et al. Electronic substituent effects on hydrogen-bonding motifs modulate supramolecular polymerisation. . RSC Advances. 2013, 3 (9), 3103-8.
Hazard Statements: H302-H331-H315-H319-H334-H335
Harmful if swallowed. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation.
Precautionary Statements: P260-P201-P280h-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.