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L10767 Propiolaldehyde diethyl acetal, 97%

CAS Number
10160-87-9
Synonyms
3,3-Diethoxy-1-propyne
Propargylaldehyde diethyl acetal

Stock No. Size Price ($) Quantity Availability
L10767-03 1g 42.20
L10767-06 5g 139.00
L10767-14 25g 404.00
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Propiolaldehyde diethyl acetal, 97%

MDL
MFCD00009237
EINECS
233-430-4

Chemical Properties

Formula
HC≡CCH(OCH2CH3)2
Formula Weight
128.17
Boiling Point
138-139°
Flash Point
32°(89°F)
Density
0.894
Refractive Index
1.4120
Storage & Sensitivity
Keep Cold.
Solubility
Slightly soluble in water.

Applications

Propiolaldehyde diethyl acetal is used in preparation of 3-boronoacrolein pinacolate, a heterodyne and (E)-3-(tributylstannyl)-2-propenal.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature is 2 - 8°C. Air and moisture sensitive. Store under inert gas.

Literature References

Xuri Gao.; Dennis G Hall. 3-Boronoacrolein as an exceptional heterodiene in the highly enantio- and diastereoselective Cr(III)-catalyzed three-component [4+2]/allylboration.. Journal of the American Chemical Society. 2003, 125 (31), 9308-9309.

Roswitha Ostwald.; Pierre-Yves Chavant.; Heinz Stadtmueller.; Paul Knochel. Catalytic Asymmetric Addition of Polyfunctional Dialkylzincs to .beta.-Stannylated and .beta.-Silylated Unsaturated Aldehydes. J. Org. Chem. 1994, 59 (15), 4143-4153.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1701566
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2911.00
TSCA
No

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