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1,1-Dibromo-3,3,3-trifluoroacetone readily forms trifluoropyruvaldehyde hydrate in the presence of aqueous NaOAc, which is a useful intermediate, e.g. in the synthesis of a fused pyrazine derivative.
David Cardoza.; Brett J. Pearson.; Mark Baertschy.; Thomas Weinacht. Charge-transfer as a mechanism for controlling molecular fragmentation. Journal of Photochemistry and Photobiology A: Chemistry. 2006, 180 (3), 277-281.
Alain Dhainaut.; André Tizot.; Eric Raimbaud .;Brian Lockhart.; Pierre Lestage.; Solo Goldstein. Synthesis, Structure, and Neuroprotective Properties of Novel Imidazolyl Nitrones. J. Med. Chem. 2000, 443 (11), 2165-2175.
In the presence of aqueous NaOAc, readily forms trifluoropyruvaldehyde hydrate, which is a useful intermediate, e.g. in the synthesis of a fused pyrazine derivative: J. Org. Chem., 58, 4033 (1993).
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.