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2-Fluoro-1-methylpyridinium p-toluenesulfonate Is a peptide coupling reagent. Also used in the synthesis of ? -ribonucleotides.
Peter G. Odell; Richard P. N. Veregin; Lora M. Michalak; and Michael K. Characteristics of the Stable Free Radical Polymerization of Styrene in the Presence of 2-Fluoro-1-methylpyridinium p-Toluenesulfonate. Macromolecules. 1997, 30, (8), 2232-2237.
J. Martin E. Quirke; Christopher L. Adams; Gary J. Van Berkel. Chemical Derivatization for Electrospray Ionization Mass Spectrometry. 1. Alkyl Halides, Alcohols, Phenols, Thiols, and Amines. Anal. Chem. 1994, 66, (8), 1302-1315.
Peptide coupling reagent. For peptide reagents, see Appendix 6. Also used in the synthesis of ɑ -ribonucleotides: Chem. Lett., 547 (1984).
Review of synthetic reactions of onium salts of aza-arenes: Angew. Chem. Int. Ed., 18, 707 (1979).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.