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86521-05-3 - 2-(Trimethylsilylethynyl)pyridine, 97% - L11251 - Alfa Aesar

L11251 2-(Trimethylsilylethynyl)pyridine, 97%

CAS Number
86521-05-3
Synonyms

Size Price ($) Quantity Availability
1g 46.14
5g 160.68
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2-(Trimethylsilylethynyl)pyridine, 97%

MDL
MFCD00066349
EINECS
000-000-0

Chemical Properties

Formula
C10H13NSi
Formula Weight
175.31
Melting point
40-43°
Boiling Point
85-86°/1mm
Refractive Index
1.5330
Solubility
Insoluble in water.

Applications

2-(Trimethylsilylethynyl)pyridine is used as a pharmaceutical intermediate.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Jesus A. Varela.; Carlos Saa. Construction of Pyridine Rings by Metal-Mediated [2?+?2?+?2] Cycloaddition. Chem. Rev. 2003, 103 (9), 3787-3802.

Mate Erdelyi.; Adolf Gogoll. Rapid Homogeneous-Phase Sonogashira Coupling Reactions Using Controlled Microwave Heating. J. Org. Chem. 2001, 66 (12), 4165-4169.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Other References

Beilstein
4176916
Harmonized Tariff Code
2933.39
TSCA
No

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