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L11510 Bis(2-bromoethyl) ether, 95%

CAS Number
5414-19-7
Synonyms
2-Bromoethyl ether
2,2'-Dibromodiethyl ether

Stock No. Size Price ($) Quantity Availability
L11510-06 5g 46.50
L11510-14 25g 123.00
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Bis(2-bromoethyl) ether, 95%

MDL
MFCD00039196
EINECS
226-504-2

Chemical Properties

Formula
BrCH2CH2OCH2CH2Br
Formula Weight
231.93
Boiling Point
92-93°/12mm
Flash Point
85°(185°F)
Density
1.845
Refractive Index
1.5140
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix with water.

Applications

Bis(2-bromoethyl) ether is used dfor synthesis of heterocyclic and crown ether. It is also used as a pharmaceutical intermediate.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases.

Literature References

William A. Nugent. An Amino Alcohol Ligand for Highly Enantioselective Addition of Organozinc Reagents to Aldehydes:? Serendipity Rules. Org. Lett. 2002, 4 (13 ), 2133-2136.

Dieter Sellmann.; Herbert Kunstmann.; Falk Knoch.; Matthias Moll. Transition-metal complexes with sulfur ligands. Part 37. Iron, molybdenum, and ruthenium complexes with pentadentate OS4 and NHS4 ligands combining thiolato, thioether, and ether or amine donor functions: synthesis, structures, and reactivity of carbon monoxide, nitric oxide, trimethylphosphine and hydrazine derivatives. Inorg. Chem. 1988, 27 (23), 4183-4190.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H318-H335

Combustible liquid. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P312-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1098335
Harmonized Tariff Code
2909.19
TSCA
Yes

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