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5414-19-7 - Bis(2-bromoethyl) ether, 96% - 2-Bromoethyl ether - 2,2'-Dibromodiethyl ether - L11510 - Alfa Aesar

L11510 Bis(2-bromoethyl) ether, 96%

CAS Number
5414-19-7
Synonyms
2-Bromoethyl ether
2,2'-Dibromodiethyl ether

Size Price ($) Quantity Availability
5g 43.36
25g 115.36
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Bis(2-bromoethyl) ether, 96%

MDL
MFCD00039196
EINECS
226-504-2

Chemical Properties

Formula
BrCH2CH2OCH2CH2Br
Formula Weight
231.93
Boiling Point
92-93°/12mm
Flash Point
85°(185°F)
Density
1.845
Refractive Index
1.5140
Solubility
Not miscible or difficult to mix with water.

Applications

Bis(2-bromoethyl) ether is used dfor synthesis of heterocyclic and crown ether. It is also used as a pharmaceutical intermediate.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases.

Literature References

William A. Nugent. An Amino Alcohol Ligand for Highly Enantioselective Addition of Organozinc Reagents to Aldehydes:? Serendipity Rules. Org. Lett. 2002, 4 (13 ), 2133-2136.

Dieter Sellmann.; Herbert Kunstmann.; Falk Knoch.; Matthias Moll. Transition-metal complexes with sulfur ligands. Part 37. Iron, molybdenum, and ruthenium complexes with pentadentate OS4 and NHS4 ligands combining thiolato, thioether, and ether or amine donor functions: synthesis, structures, and reactivity of carbon monoxide, nitric oxide, trimethylphosphine and hydrazine derivatives. Inorg. Chem. 1988, 27 (23), 4183-4190.

GHS Hazard and Precautionary Statements

Hazard Statements: H318-H315-H335-H227

Causes serious eye damage. Causes skin irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P310-P362-P312-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1098335
Hazard Class
6.1
Harmonized Tariff Code
2909.19
TSCA
Yes

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