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L11556 Propargyl methacrylate, 98%, stab. with 200-300ppm 4-methoxyphenol

CAS Number
13861-22-8
Synonyms
Methacrylic acid propargyl ester
2-Propyn-1-yl 2-methylpropenoate

Stock No. Size Price ($) Quantity Availability
L11556-09 10g 85.10
L11556-18 50g 350.00
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Propargyl methacrylate, 98%, stab. with 200-300ppm 4-methoxyphenol

MDL
MFCD00048123
EINECS
237-599-5

Chemical Properties

Formula
C7H8O2
Formula Weight
124.14
Boiling Point
149-151°
Flash Point
48°(118°F)
Density
0.986
Refractive Index
1.4500
Storage & Sensitivity
Keep Cold.
Solubility
Immiscible with water.

Applications

Propargyl methacrylate is a monomer used in polymerization reactions. It is associated with its acetylene and under goes polymerization reaction through the reversible addition fragmentation chain transfer (RAFT) process using cyanoisopropyl dithiobenzoate as a reagent.

Notes

Incompatible with oxidizing agents.

Literature References

Ma, W.; Chen, D.; Wang, L.; Ma, Y.; Zhao, C.; Yang, W. Visible Light-Controlled Radical Polymerization of Propargyl Methacrylate Activated by a Photoredox Catalyst fac-[Ir(ppy)3]. J. Macromol. Sci. Part A Pure Appl. Chem. 2015, 52 (9), 761-769.

Prasher, A.; Loynd, C. M.; Tuten, B. T.; Frank, P. G.; Chao, D.; Berda, E. B. Efficient fabrication of polymer nanoparticles via sonogashira cross-linking of linear polymers in dilute solution. J. Polym. Sci., Part A: Polym. Chem. 2016, 54 (1), 209-217.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
906850
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2916.14
TSCA
Yes

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