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13861-22-8 - Propargyl methacrylate, 98%, stab. with 250ppm 4-methoxyphenol - Methacrylic acid propargyl ester - 2-Propyn-1-yl 2-methylpropenoate - L11556 - Alfa Aesar

L11556 Propargyl methacrylate, 98%, stab. with 250ppm 4-methoxyphenol

CAS Number
13861-22-8
Synonyms
Methacrylic acid propargyl ester
2-Propyn-1-yl 2-methylpropenoate

Size Price ($) Quantity Availability
10g 74.40
50g 308.00
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Propargyl methacrylate, 98%, stab. with 250ppm 4-methoxyphenol

MDL
MFCD00048123
EINECS
237-599-5

Chemical Properties

Formula
C7H8O2
Formula Weight
124.14
Boiling Point
149-151°
Flash Point
48°(118°F)
Density
0.986
Refractive Index
1.4500
Solubility
Immiscible with water.

Applications

Propargyl methacrylate is a monomer used in polymerization reactions. It is associated with its acetylene and under goes polymerization reaction through the reversible addition fragmentation chain transfer (RAFT) process using cyanoisopropyl dithiobenzoate as a reagent.

Notes

Incompatible with oxidizing agents.

Literature References

Ma, W.; Chen, D.; Wang, L.; Ma, Y.; Zhao, C.; Yang, W. Visible Light-Controlled Radical Polymerization of Propargyl Methacrylate Activated by a Photoredox Catalyst fac-[Ir(ppy)3]. J. Macromol. Sci. Part A Pure Appl. Chem. 2015, 52 (9), 761-769.

Prasher, A.; Loynd, C. M.; Tuten, B. T.; Frank, P. G.; Chao, D.; Berda, E. B. Efficient fabrication of polymer nanoparticles via sonogashira cross-linking of linear polymers in dilute solution. J. Polym. Sci., Part A: Polym. Chem. 2016, 54 (1), 209-217.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P305+P351+P338-P302+P352

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water.

Other References

Beilstein
906850
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2916.14
TSCA
Yes

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