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Phenyl acrylate reacts with benzaldehyde to produce 2-(hydroxy-phenyl-methyl)-acrylic acid phenyl ester.
S.-K. L. Li.; J. E. Guillet. Studies of the Photo-Fries Reaction in Solid Poly(phenyl acrylate). Macromolecules. 1977, 10 (4), 840-844.
Makoto Azukizawa.; Bunichiro Yamada.; David J. T. Hill.; Peter J. Pomery. Radical polymerization of phenyl acrylate as studied by ESR spectroscopy: concurrence of propagating and mid-chain radicals. Macromolecular Chemistry and Physics. 2000, 201 (7), 774-781.
Aryl acrylates undergo the Baylis-Hillman reaction with aldehydes in the presence of 1,4-Diazabicyclo[2.2.2]octane, A14003 much more rapidly than alkyl acrylates. Reaction with a second molecule of aldehyde can occur to give a cyclic acetal product: Tetrahedron Lett., 37, 1715 (1996):
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant