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L12117 Diethyl ethylidenemalonate, 99%

CAS Number
1462-12-0
Synonyms
Ethylidenemalonic acid diethyl ester

Stock No. Size Price ($) Quantity Availability
L12117-03 1g 20.70
L12117-06 5g 55.30
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Diethyl ethylidenemalonate, 99%

MDL
MFCD00009145
EINECS
215-965-5

Chemical Properties

Formula
C9H14O4
Formula Weight
186.21
Boiling Point
115-116°/17mm
Flash Point
>110°(230°F)
Density
1.019
Refractive Index
1.4420
Storage & Sensitivity
Ambient temperatures.

Literature References

Addition of dibromocarbene (bromoform/NaOH) gives the dibromocyclopropane in good yield: Tetrahedron Lett., 26, 6353 (1985). Reaction with propargyl bromides in the presence of zinc leads to cyclopentenes: Synthesis, 150 (1978).

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Reaction with crotyltriisopropoxytitanium produces the anti-adduct as the major product: J. Chem. Soc., Chem. Commun., 386 (1985):

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Other References

Beilstein
1773932
Harmonized Tariff Code
2917.19
TSCA
No

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