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1707-77-3 - 1,2:5,6-Di-O-isopropylidene-D-mannitol - 1,2:5,6-Diacetone-D-mannitol - L12127 - Alfa Aesar

L12127 1,2:5,6-Di-O-isopropylidene-D-mannitol

CAS Number
1707-77-3
Synonyms
1,2:5,6-Diacetone-D-mannitol

Size Price ($) Quantity Availability
5g 40.50
25g 143.00
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1,2:5,6-Di-O-isopropylidene-D-mannitol

MDL
MFCD00003211
EINECS
216-954-8

Chemical Properties

Formula
C12H22O6
Formula Weight
262.31
Melting point
120-122°

Literature References

Treatment with NaIO 4 affords the useful synthon 2,3-O-isopropylidene-D-glyceraldehyde (glyceraldehyde acetonide): J. Org. Chem., 56, 4056 (1991); Org. Synth. Coll., 9, 450 (1998). This in turn can be homologated diastereoselectively using 2-(Trimethyl­silyl)­thiazole, B21903: Org. Synth. Coll., 9, 52 (1998). For use of Pb(OAc) 4 in the formation of glyceraldehyde acetonide as a chiral precursor of cyclopropyl carbocyclic nucleosides as HIV reverse transcriptase inhibitors, see: J. Org. Chem., 60, 5236 (1995).

/n

Other References

Beilstein
83765
Harmonized Tariff Code
2932.99
TSCA
No

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