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75-78-5 - Dichlorodimethylsilane, 99% - Dimethyldichlorosilane - Dimethylsilyl dichloride - L12133 - Alfa Aesar

L12133 Dichlorodimethylsilane, 99%

CAS Number
75-78-5
Synonyms
Dimethyldichlorosilane
Dimethylsilyl dichloride

Size Price ($) Quantity Availability
100g 31.32
500g 38.01
1000g 69.53
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Dichlorodimethylsilane, 99%

MDL
MFCD00000491
EINECS
200-901-0

Chemical Properties

Formula
C2H6Cl2Si
Formula Weight
129.06
Melting point
ca -76°
Boiling Point
70-71°
Flash Point
-5°(23°F)
Density
1.068
Refractive Index
1.4045
Sensitivity
Moisture Sensitive
Solubility
Immiscible with water.

Applications

Dichlorodimethylsilane is used to prepare a resin bound siloxane with tertiary alcohols and it is also used as a reagent for synthesis of optically active ansa-mettallocene polymerization catalysts. It acts as a precursor to silicone and polysilane compounds. It is also used in the glass coating to protect it from micro particles. It is involved in the preparation of resin bound siloxane with reactivity towards tertiary alcohols.

Notes

Moisture sensitive. Store in a cool place. Incompatible with alcohols, amines and strong bases.

Literature References

Silicone intermediate and silylating agent, forming dimethylsilylene derivatives of diols. The main limitation of these is their extreme susceptibilty to hydrolysis. See Appendix 4.

For use in combination with triflic acid to generate dimethyldisilyl triflate, and its use in synthesis, see N,N'-Diacetyl­hydrazine, A13393 .

Kim, Y. R.; Lai, S. C. S.; McKelvey, K.; Zhang, G.; Perry, D.; Miller, T. S.; Unwin, P. R. Nucleation and aggregative growth of palladium nanoparticles on carbon electrodes: experiment and kinetic model. J. Phys. Chem. C 2015, 119 (30), 17389-17397.

Wang, Z.; Gong, X.; Ngai, T. Measurements of Long-Range Interactions between Protein-Functionalized Surfaces by Total Internal Reflection Microscopy. Langmuir. 2015, 31 (10), 3101-3107.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H331-H319-H335-H314

Highly flammable liquid and vapour. Toxic if inhaled. Causes serious eye irritation. May cause respiratory irritation. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
605287
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
VV3150000

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