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Methyl 2-isocyanatobenzoate is used for the following syntheses 3H-quinazolin-4-ones, A1120, a high affinity (Ki = 8.3nM) non-retinoid ligand for the Retinol-binding protein, trans- and cis-N-phenyl-N?-(4-phenoxy)cyclohexylureas.
Alexander V Lygin; Armin de Meijere. ortho-Lithiophenyl isocyanide: a versatile precursor for 3H-quinazolin-4-ones and 3H-quinazolin-4-thiones. Organic Letters.2009, 11, (2), 389-392.
Hazard Statements: H302-H331-H315-H319-H334-H335
Harmful if swallowed. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation.
Precautionary Statements: P284-P261-P280a-P305+P351+P338-P405-P501a
Wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.