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1793-07-3 - 2-(Methoxycarbonyl)phenyl isocyanate, 97% - 2-(Carbomethoxy)phenyl isocyanate - Methyl 2-isocyanatobenzoate - L12471 - Alfa Aesar

L12471 2-(Methoxycarbonyl)phenyl isocyanate, 97%

CAS Number
1793-07-3
Synonyms
2-(Carbomethoxy)phenyl isocyanate
Methyl 2-isocyanatobenzoate

Size Price ($) Quantity Availability
1g 27.90
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2-(Methoxycarbonyl)phenyl isocyanate, 97%

MDL
MFCD00013848

Chemical Properties

Formula
C9H7NO3
Formula Weight
177.16
Melting point
45-49°
Boiling Point
145-146°/16mm
Sensitivity
Moisture Sensitive
Solubility
Hydrolyzes in water.

Applications

Methyl 2-isocyanatobenzoate is used for the following syntheses 3H-quinazolin-4-ones, A1120, a high affinity (Ki = 8.3nM) non-retinoid ligand for the Retinol-binding protein, trans- and cis-N-phenyl-N?-(4-phenoxy)cyclohexylureas.

Notes

Moisture Sensitive. Incompatible with bases, alcohols and amines. Store under dry inert gas. Protect from humidity and water. Store away from moisture.

Literature References

Alexander V Lygin; Armin de Meijere. ortho-Lithiophenyl isocyanide: a versatile precursor for 3H-quinazolin-4-ones and 3H-quinazolin-4-thiones. Organic Letters.2009, 11, (2), 389-392.

GHS Hazard and Precautionary Statements

Hazard Statements: H331-H302-H315-H319-H335-H334

Toxic if inhaled. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary Statements: P285-P261-P280-P305+P351+P338-P304+P340-P311-P342+P311-P362-P405-P501a

In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. If experiencing respiratory symptoms: Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1241370
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2929.10
TSCA
No

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