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L12766 4-Bromo-1,1,2-trifluoro-1-butene, 98%

CAS Number
10493-44-4
Synonyms

Stock No. Size Price ($) Quantity Availability
L12766-09 10g 63.90
L12766-18 50g 232.00
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4-Bromo-1,1,2-trifluoro-1-butene, 98%

MDL
MFCD00039274
EINECS
234-019-2

Chemical Properties

Formula
C4H4BrF3
Formula Weight
188.98
Boiling Point
95-98°
Flash Point
17°(62°F)
Density
1.639
Refractive Index
1.4020
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

4-Bromo-1,1,2-trifluoro-1-butene is used in organic synthesis, chemical research and pharmaceuticals.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Literature References

Noritada Matsuo.; Andrew S. Kende. 1,1,2-Trifluoro-1,3-butadiene: a convenient C4 intermediate for functionalized monofluoroolefins. J. Org. Chem. 1988, 53 (10), 2 304-2308.

Dorothea Golze.; Maik Icker.; Stefan Berger. Implementation of two-qubit and three-qubit quantum computers using liquid-state nuclear magnetic resonance. Concepts in Magnetic Resonance Part A. 2012, 40A (1), 25-37.

Precursor, by dehydrobromination under phase-transfer conditions, of 1,1,2-trifluoro-1,3-butadiene, a convenient C4 intermediate for functionalized monofluoroolefins: J. Org. Chem., 53, 2304 (1988).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1840755
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.79
TSCA
No

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