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5296-62-8 - Allyl ethyl sulfide, 97% - 3-Ethylthio-1-propene - L12847 - Alfa Aesar

L12847 Allyl ethyl sulfide, 97%

CAS Number
5296-62-8
Synonyms
3-Ethylthio-1-propene

Size Price ($) Quantity Availability
1g 30.40
5g 87.60
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Allyl ethyl sulfide, 97%

MDL
MFCD00026979

Chemical Properties

Formula
C5H10S
Formula Weight
102.19
Boiling Point
115-116°
Flash Point
18°(64°F)
Density
0.868
Refractive Index
1.4680

Literature References

The lithiated derivative can react with electrophiles at either the ɑ- or - postion. It was found that conversion of the organolithium to an organotitanium reagent (by reaction with Ti(O-iPr)4), followed by reaction with e.g. cyclohexanecarboxaldehyde resulted in regioselective reaction at the ɑ-position to give the corresonding hydroxy sulfide: Bull. Chem. Soc. Jpn., 57, 2781 (1984). For review of allylic and benzylic carbanions substituted by heteroatoms, see: Org. React., 27, 1 (1982).

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GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280g-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1736876
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2930.90
TSCA
No

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