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6-Bromo-1-hexene was used in the preparation of epoxide, 6-bromo-1,2-epoxyhexane. It was also used in a simple, direct preparation of 4-alkenylbenzonitriles via anionic reduced forms of terephthalonitrile in liquid ammonia.
James H.Babler; William E.Bauta. Cyclization of 6-bromo-1,2-epoxyhexane promoted by metal-halogen exchange: unexpected regioselectivity. Tetrahedron Letters. 1984, 25,(39), 4323-4324.
David M.Fang; Dennis G.Peters; Mohammad S.Mubarak. Catalytic reduction of 6-bromo-1-hexene by nickel (I) salen electrogenerated at glassy carbon cathodes in acetonitrile. J. Electrochem. Soc. 2001, 148,(12), E464-E467.
Hazard Statements: H226-H315-H319-H335
Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280g-P305+P351+P338
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.