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L12909 6-Bromo-1-hexene, 95%

CAS Number
2695-47-8
Synonyms

Stock No. Size Price ($) Quantity Availability
L12909-03 1g 39.40
L12909-06 5g 144.00
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6-Bromo-1-hexene, 95%

MDL
MFCD00000269
EINECS
220-267-9

Chemical Properties

Formula
C6H11Br
Formula Weight
163.06
Boiling Point
147°
Flash Point
54°(129°F)
Density
1.217
Refractive Index
1.4652
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible in water.

Applications

6-Bromo-1-hexene was used in the preparation of epoxide, 6-bromo-1,2-epoxyhexane. It was also used in a simple, direct preparation of 4-alkenylbenzonitriles via anionic reduced forms of terephthalonitrile in liquid ammonia.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

James H.Babler; William E.Bauta. Cyclization of 6-bromo-1,2-epoxyhexane promoted by metal-halogen exchange: unexpected regioselectivity. Tetrahedron Letters. 1984, 25,(39), 4323-4324.

 

David M.Fang; Dennis G.Peters; Mohammad S.Mubarak. Catalytic reduction of 6-bromo-1-hexene by nickel (I) salen electrogenerated at glassy carbon cathodes in acetonitrile. J. Electrochem. Soc. 2001, 148,(12), E464-E467.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
506203
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2903.39
TSCA
Yes

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