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James A. Marshall.; Thomas M. WarneJr. Total synthesis of (+-)-isonootkatone. Stereochemical studies of the Robinson annelation reaction with 3-penten-2-one. J. Org. Chem. 1971, 36 (1), 178-183.
J. Peter Guthrie. The retroaldol reaction of 3-penten-2-one: equilibrium constant for hydration and rate constants for the hydration and retroaldol reactions in base. Canadian Journal of Chemistry. 1981, 59 (1), 45-49.
Undergoes conjugate addition with Ethyl nitroacetate, A14433. The resulting -nitro ketone can be reductively cyclized to a pyrrole in high yield: Tetrahedron Lett., 36, 9469 (1995):
Hazard Statements: H225-H303-H311-H315-H319-H335
Highly flammable liquid and vapour. May be harmful if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.