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L13177 Borane-tert-butylamine complex, 97%

CAS Number
7337-45-3
Synonyms
tert-Butylamine-borane

Stock No. Size Price ($) Quantity Availability
L13177-09 10g 30.00
L13177-18 50g 82.90
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Borane-tert-butylamine complex, 97%

MDL
MFCD00075635
EINECS
230-851-5

Chemical Properties

Formula
(CH3)3CNH2.BH3
Formula Weight
86.98
Melting point
96-98°
Density
0.870
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (27 g/L at 20°C) and methanol.

Applications

Borane-tert-butylamine complex is used in stereoselective reduction of a steroidal ketone and for a review of amine boranes as selective reducing and hydroborating agents. It is also used as strong co-reducing agent in the syntheses of copper (I) oxide nanoparticles, diphosphine-protected gold nanocluster and 4-acetoxycinnamyl alcohols.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and acids.

Literature References

John M Pettibone.; Jeffrey W Hudgens. Reaction network governing diphosphine-protected gold nanocluster formation from nascent cationic platforms. Physical Chemistry Chemical Physics. 2012, 14 (12), 4142-4154.

Na Rae Kim.; Inyu Jung.; Yun Hwan Jo.; Hyuck Mo Lee. A simple process for the preparation of copper (I) oxide nanoparticles by a thermal decomposition process with borane tert-butylamine complex. Journal of Nanoscience and Nanotechnology. 2013, 13 (9), 6027-6032.

Solid, water-soluble reducing agent. For use in stereoselective reduction of a steroidal ketone, see: Synth. Commun., 11, 875 (1981). Reduces aldehydes, generated in situ by hydrolysis of acetals with aqueous triflic acid in THF, to primary alcohols: Synlett, 59 (1999). For a review of amine boranes as selective reducing and hydroborating agents, see: Org. Prep. Proced. Int., 16, 335 (1984).

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H301-H311-H314-H332-H335

Flammable solid. Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P240-P241-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
4134905
Hazard Class
4.1
Packing Group
II
Harmonized Tariff Code
2942.00
TSCA
Yes
RTECS
EO3900000

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