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20989-17-7 - (S)-(+)-2-Phenylglycinol, 98+% - (S)-(+)-2-Amino-2-phenylethanol - H-Phg-ol - L13265 - Alfa Aesar

L13265 (S)-(+)-2-Phenylglycinol, 98+%

CAS Number
20989-17-7
Synonyms
(S)-(+)-2-Amino-2-phenylethanol
H-Phg-ol

Size Price ($) Quantity Availability
1g 38.00
5g 111.00
25g 393.00
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(S)-(+)-2-Phenylglycinol, 98+%

MDL
MFCD00064404

Chemical Properties

Formula
C8H11NO
Formula Weight
137.18
Melting point
76-78°
Sensitivity
Air Sensitive
Solubility
Soluble in chloroform, dimethylsulfoxide and methanol. Limited solubility in water.

Applications

(S)-(+)-2-Phenylglycinol is used in the synthesis of chiral, unsymmetrical bisoxazolines. It is used as a reagent for the resolution of acids via the easily hydrolyzed amides.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is sensitive to air. Incompatible with oxidizing agents. Store at -20°C.

Literature References

Pradeep, Chullikkattil P.; Zacharias, Panthapally S.; Das, Samar K. Synthesis and characterization of a chiral dimeric copper(II) complex: Crystal structure of [Cu2(?-Cl)2(HL)2]· H2O(H2L = S-(-)-2-[(2-hydroxy-1-phenyl-ethylimino)-methyl]-phenol). Journal of Chemical Sciences. 2005, 117 (2), 133-137.

Reagent for the resolution of acids via the easily hydrolyzed amides: J. Org. Chem ., 51, 4836 (1986).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3196190
Harmonized Tariff Code
2922.19
TSCA
No

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