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L13278 Sodium cyanide, granules, 98%

CAS Number

Stock No. Size Price ($) Quantity Availability
L13278-18 50g 25.80
L13278-30 250g 33.50
L13278-0B 1000g 64.90
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Sodium cyanide, granules, 98%


Chemical Properties

Formula Weight
Melting point
Boiling Point
ca 1500°
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Soluble in water, ammonia, methanol and ethanol. Slightly soluble in dimethylformamide. Insoluble in dimethylsulphoxide.


Sodium cyanide is used as a starting material for the preparation of Reissert compounds and cyanogen bromide, cyanuric chloride and cyanogen chloride. It acts as a catalyst for the aminolysis of esters to primary amides. Furthermore, it is used for fumigation, electroplating, extracting gold and silver in mining industry. In organic synthesis, it is involved in the cyanation reaction of alkyl halides under phase transfer conditions.


Hygroscopic. Do not store near acids. Incompatible with strong oxidizing agents and carbon dioxide.

Literature References

Cyanations of alkyl halides are often carried out most conveniently under phase-transfer conditions: Synth. Commun., 6, 193 (1976); see: E. V. Dehmlow and S. S. Dehmlow, Phase-Transfer Catalysis, 3rd ed., VCH, N.Y. (1993), for further extensive examples. DMSO is also a good solvent for these reactions: J. Org. Chem., 25, 257, 877 (1960).

For formation of Reissert compounds, see Quinoline, A11545.

Mild catalyst for the aminolysis of esters to primary amides: J. Org. Chem., 52, 2033 (1987).

For generation of cyanogen bromide by reaction with bromine, see: Org. Synth. Coll ., 7, 435 (1990).

See also Potassium cyanide, L13273.

Murahashi, S. I.; Nakae, T.; Terai, H.; Komiya, N. Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3 C-H Bond Activation and Carbon- Carbon Bond Formation. J. Am. Chem. Soc. 2008, 130 (33), 11005-11012.

Singhal, S.; Jain, S. L.; Sain, B. An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts. Chem. Commun. 2009, 17, 2371-2372.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H300-H310-H330-H372

May be corrosive to metals. Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P234-P260-P262-P264b-P270-P271-P280-P284-P301+P310-P302+P350-P304+P340-P310-P312-P314-P330-P361-P363-P390-P501c

Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Gently wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. Rinse mouth. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


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    Copper(I) cyanide
  • 13432

    Sodium borohydride, 98%

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