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L13328 Biphenyl-4,4'-diboronic acid, 95%

CAS Number
4151-80-8
Synonyms
Biphenyl-4,4'-diylbisboronic acid

SDS Certificate of Analysis Product Specification Technical Inquiry
Stock No. Size Price ($) Quantity Availability
L13328-03 1g 116.00
L13328-06 5g 433.00
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Biphenyl-4,4'-diboronic acid, 95%

MDL
MFCD00151795
EINECS
000-000-0

Chemical Properties

Formula
C12H12B2O4
Formula Weight
241.85
Melting point
ca 300° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

Biphenyl-4,4'-diboronic acid is used in the preparation of cycloparaphenylenes through Suzuki coupling. It is also employed in the synthesis of 1,3,2-diazaboroine derivatives, which is useful for organic thin-film transistor applications. It plays an important role in the preparation of arylboronates from reactions with catechol, dihydroxynaphthalene and diaminobenzenedithiol, which finds application as organic field-effect transistors and light emitting diodes.

Notes
Incompatible with strong oxidizing agents.

Literature References

Du, Y.; Mao, K.; Kamakoti, P.; Wooler, B.; Cundy, S.; Li, Q.; Ravikovitch, P.; Calabro, D. The effects of pyridine on the structure of B-COFs and the underlying mechanism. J. Mater. Chem. A 2013, 1 (42), 13171-13178.

Du, Y.; Mao, K.; Kamakoti, P.; Ravikovitch, P.; Paur, C.; Cundy, S.; Li, Q.; Calabro, D. Experimental and computational studies of pyridine-assisted post-synthesis modified air stable covalent-organic frameworks. Chem. Commun. 2012, 48 (38), 4606-4608.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2941876
Harmonized Tariff Code
2931.90
TSCA
No

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