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109-72-8 - n-Butyllithium, 1.6M in hexane, packaged in resealable septum cap bottle - L13559 - Alfa Aesar

L13559 n-Butyllithium, 1.6M in hexane, packaged in resealable septum cap bottle

CAS Number
109-72-8
Synonyms

n-Butyllithium, 1.6M in hexane, packaged in resealable septum cap bottle

MDL
MFCD00009414
EINECS
203-698-7

Chemical Properties

Formula
C4H9Li
Formula Weight
64.06
Flash Point
-22°(-8°F)
Density
0.680
Sensitivity
Air & Moisture Sensitive

Notes

Haziness and precipitate may form upon storage but does not affect specification.

Literature References

Numerous examples of the use of n-BuLi are to be found in Org. Synth. Coll., 7 (1990), 8, (1993), 9 (1998) and in subsequent annual volumes.

/n

There are also many examples throughout this catalog. For a useful monograph with many practical procedures, see: B. J. Wakefield, Organolithium Methods, Academic Press, N.Y. (1988).

/n

See also N,N,N',N'-Tetramethyl­ethyl­enediamine, A12536.

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H250-H260-H252-H304-H361-H373-H314-H336-H411

Highly flammable liquid and vapour. Catches fire spontaneously if exposed to air. In contact with water releases flammable gases which may ignite spontaneously. Self-heating in large quantities; may catch fire. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects.

Precautionary Statements: P210-P222-P231+P232-P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P422a-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Store contents under inert gas. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1209227
Hazard Class
4.2
Packing Group
I
Harmonized Tariff Code
2931.90
TSCA
Yes

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