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622-33-3 - O-Benzylhydroxylamine, 96% - L13601 - Alfa Aesar

L13601 O-Benzylhydroxylamine, 96%

CAS Number
622-33-3
Synonyms

Size Price ($) Quantity Availability
5g 55.10
25g 195.00
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O-Benzylhydroxylamine, 96%

MDL
MFCD00221709

Chemical Properties

Formula
C7H9NO
Formula Weight
123.15
Boiling Point
118-119°/30mm
Density
1.058
Refractive Index
1.5410
Solubility
Soluble in dimethylsulfoxide and methanol.

Applications

O-benzylhydroxylamine used in the synthesis of alfa- hydroxybenzylamines from alfa-hydroxyketones. It is also involved in the preparation of hydroxylamines and hydroxyamates.

Notes

Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Jobbins, M. O.; Majewski, M. W.; Oliver, A. G.; Miller, M. J. Diastereoselective synthesis of a hydroxamate containing bicyclo-[3.2. 0] beta-lactam aminal via ruthenium alkene isomerization and Pd(II)-catalyzed oxidative amidation. Tetrahedron Lett. 2015, 56 (23), 3141-3143.

Jeon, M.; Gupta, S.; Im, Y. W.; Rhee, Y. H.;Park, J. Fast and Complete Transimination of N-H Imines into O-Alkyl Oximes. Asian J. Org. Chem. 2015, 4 (4), 316-319.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1906691
Harmonized Tariff Code
2928.00
TSCA
No

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