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100-61-8 - N-Methylaniline, 98% - Monomethylaniline - L13873 - Alfa Aesar

L13873 N-Methylaniline, 98%

CAS Number
100-61-8
Synonyms
Monomethylaniline

Size Price ($) Quantity Availability
100g 19.80
500g 30.69
2500g 114.33
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N-Methylaniline, 98%

MDL
MFCD00008283
EINECS
202-870-9

Chemical Properties

Formula
C7H9N
Formula Weight
107.16
Melting point
-57°
Boiling Point
194-197°
Flash Point
86°(186°F)
Density
0.989
Refractive Index
1.5710
Sensitivity
Air Sensitive
Solubility
Immiscible with water.

Applications

N-Methylaniline is used in the preparation of N,N'-dimethylsulfinyldianilin using triethylamine and thionyl chloride as reagents. It is also acts as a latent and coupling solvent. Further, it serves as an intermediate for dyes and agrochemicals. In addition to this, it is utilized as an antiknock agent, which plays an essential role to increase the octane number.

Notes

Incompatible with strong oxidizing agents, acids, acid anhydrides, acid chlorides and carbon dioxide.

Literature References

N-Alkylanilines react with triethanolamine in dioxan (autoclave) in the presence of Dichlorotris(triphenyl­phosphine)­ruthenium(II)­, L00373, to give the corresponding 1-alkylindole in good yield: Synth. Commun., 26, 1349 (1996).

Emel’yanenko, V. N.; Pimerzin, A. A.; Turovtsev, V. V.; Verevkin, S. P. Benchmark Thermochemistry of N-Methylaniline. J. Phys. Chem. A 2015, 119 (10), 2142-2152.

Belyaeva, E. I.; Zrelova, L. V.; Marchenko, D. Y.; Dedov, A. G. Colorimetric determination of N-methylaniline in hydrocarbon media. Petro. Chem. 2015, 55 (1), 74-79.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H331-H373-H400-H410-H227

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Combustible liquid.

Precautionary Statements: P210-P260-P261-P273-P280-P301+P310-P361-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,6019
Beilstein
741982
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.42
TSCA
Yes
RTECS
BY4550000

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