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L14049 Ethyl hexafluoroglutaryl chloride, 97%

CAS Number
18381-53-8
Synonyms
4-Carboethoxyhexafluorobutyryl chloride
Hexafluoroglutaric acid monoethyl ester chloride

Stock No. Size Price ($) Quantity Availability
L14049-MD 250mg 37.90
L14049-06 5g 291.00
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Ethyl hexafluoroglutaryl chloride, 97%

MDL
MFCD00054671

Chemical Properties

Formula
C7H5ClF6O3
Formula Weight
286.56
Boiling Point
158-160°
Density
1.470
Refractive Index
1.3590
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Miscible with water.

Applications

Ethyl hexafluoroglutaryl chloride is used as a derivatising agent in gas chromatography. It is an active reagent used for the quantization of amphetamine and methamphetamine in urine by gas chromatography/mass spectroscopy (GC/MS).

Notes

Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, bases and water.

Literature References

Pace, A.; Buscemi, S.; Vivona, N. The synthesis of fluorinated heteroaromatic compounds. Part 1. Five-membered rings with more than two heteroatoms. Org. Prep. Proc. Int. 2005, 37 (5), 447-506.

Prakash, G. S.; Hu, J.; Olah, G. A. Alkylation of in situ generated fluorinated alkoxides: novel synthesis of partially fluorinated ethers. Arkivoc 2003, 3, 104-119.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1884844
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2917.19
TSCA
No

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