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3395-91-3 - Methyl 3-bromopropionate, 97% - 3-Bromopropionic acid methyl ester - L14127 - Alfa Aesar

L14127 Methyl 3-bromopropionate, 97%

CAS Number
3395-91-3
Synonyms
3-Bromopropionic acid methyl ester

Size Price ($) Quantity Availability
25g 49.30
100g 133.00
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Methyl 3-bromopropionate, 97%

MDL
MFCD00000250
EINECS
222-247-5

Chemical Properties

Formula
Br(CH2)2CO2CH3
Formula Weight
167.01
Boiling Point
58-60°/12mm
Flash Point
75°(167°F)
Density
1.530
Refractive Index
1.4580
Solubility
Immiscible in water.

Applications

Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones. It can react with 2-Methyl-1H-benzoimidazole to get 1-(2-Methoxycarbonylethyl)-2-methylbenzimidazole.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Literature References

Adriana Pohlmann; Vincent Schanen; Dominique Guillaume; Jean-Charles Quirion; and Henri-Philippe Husson. Efficient Synthesis of Conformationally Constrained Peptidomimetics Containing 2-Oxopiperazines1. J. Org. Chem, 1997, 62, (4), 1016-1022.

Ren?suk; Zhong Hua; Mohamed Abdou; Christoph Kratky. Samarium diiodide promoted spirolactonization of cycloalkanones. Tetrahedron. 1991, 47, (34), 7037-7044.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H301-H315-H319-H335

Combustible liquid. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210u-P261-P301+P310a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1742949
Harmonized Tariff Code
2915.50
TSCA
Yes
RTECS
UA2451790

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