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L14137 (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%

CAS Number
35193-64-7
Synonyms
(S)-(+)-1,1'-Binaphthalene-2,2'-diyl hydrogen phosphate
(S)-(+)-BNP acid

Stock No. Size Price ($) Quantity Availability
L14137-MD 250mg 27.20
L14137-03 1g 56.20
L14137-06 5g 167.00
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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%

MDL
MFCD00010045

Chemical Properties

Formula
C20H13O4P
Formula Weight
348.30
Melting point
>300°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in DMSO and methanol (hot).

Applications

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Literature References

Masahiro Yamanaka; Junji Itoh; Kohei Fuchibe; Takahiko Akiyama. Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction. Journal of the American Chemical Society. 2007, 129, (21), 6756-6764.

B Chankvetadze; M Saito; E Yashima; Y Okamoto. Enantioseparation using selected polysaccharides as chiral buffer additives in capillary electrophoresis. Journal of Chromatography A. 1997, 773, (1-2), 331-338.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
4787775
Harmonized Tariff Code
2919.90
TSCA
No

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