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39637-74-6 - (1S)-(-)-Camphanic chloride, 95% - (-)-Camphanic acid chloride - L14148 - Alfa Aesar

L14148 (1S)-(-)-Camphanic chloride, 95%

CAS Number
39637-74-6
Synonyms
(-)-Camphanic acid chloride

Size Price ($) Quantity Availability
1g 31.20
5g 146.26
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(1S)-(-)-Camphanic chloride, 95%

MDL
MFCD00135626
EINECS
254-552-4

Chemical Properties

Formula
C10H13ClO3
Formula Weight
216.67
Melting point
64-68°
Sensitivity
Moisture Sensitive
Solubility
Soluble in dichloromethane, ether, ethyl acetate and methanol. Reacts with water.

Applications

(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2 - 8°C. Store under inert gas. It is sensitive to moisture. Protect from humidity and water. Incompatible with bases and oxidizing agents.

Literature References

Demetrios N Nicolaides.; Daman R Gautam.; Konstantinos E Litinas.; Dimitra J Hadjipavlou-Litina.; Konstantina C Fylaktakidou. Synthesis and evaluation of the antioxidant and antiinflammatory activities of some benzo[l]khellactone derivatives and analogues. European Journal of Medicinal Chemistry. 2004, 39 (4 ), 323-332.

Andrew M. Riley.; H. Yasmin Godagea.; Mary F. Mahonb.; Barry V.L. Potter. Chiral desymmetrisation of myo-inositol 1,3,5-orthobenzoate gives rapid access to precursors for second messenger analogues. Tetrahedron: Asymmetry. 2006, 17 (2), 171-174.

Resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography: Helv. Chim. Acta, 51, 1587 (1968); 61, 2773 (1978).

Chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3590860
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2932.99
TSCA
No

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