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(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Demetrios N Nicolaides.; Daman R Gautam.; Konstantinos E Litinas.; Dimitra J Hadjipavlou-Litina.; Konstantina C Fylaktakidou. Synthesis and evaluation of the antioxidant and antiinflammatory activities of some benzo[l]khellactone derivatives and analogues. European Journal of Medicinal Chemistry. 2004, 39 (4 ), 323-332.
Andrew M. Riley.; H. Yasmin Godagea.; Mary F. Mahonb.; Barry V.L. Potter. Chiral desymmetrisation of myo-inositol 1,3,5-orthobenzoate gives rapid access to precursors for second messenger analogues. Tetrahedron: Asymmetry. 2006, 17 (2), 171-174.
Resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography: Helv. Chim. Acta, 51, 1587 (1968); 61, 2773 (1978).
Chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Hazard Statements: H314-H335
Causes severe skin burns and eye damage. May cause respiratory irritation.
Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant