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3976-69-0 - Methyl (R)-(-)-3-hydroxybutyrate, 98% - (R)-(-)-3-Hydroxybutyric acid methyl ester - L14151 - Alfa Aesar

L14151 Methyl (R)-(-)-3-hydroxybutyrate, 98%

CAS Number
3976-69-0
Synonyms
(R)-(-)-3-Hydroxybutyric acid methyl ester

Size Price ($) Quantity Availability
1g 28.40
5g 82.70
25g 282.00
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Methyl (R)-(-)-3-hydroxybutyrate, 98%

MDL
MFCD00063289
EINECS
223-610-0

Chemical Properties

Formula
C5H10O3
Formula Weight
118.13
Boiling Point
56-58°/11mm
Flash Point
73°(163°F)
Density
1.055
Refractive Index
1.4220
Solubility
Slightly soluble in water.

Applications

Can undergo aldol-type reactions with aldehydes with either syn- or anti-selectivity according to the conditions, for use in the synthesis of chiral ß-lactams.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Literature References

Xiao-Hong Chen; Ping Wei; Xiao-Ting Wang; Min-Hua Zong; Wen-Yong Lou. A novel carbonyl reductase with anti-Prelog stereospecificity from Acetobacter sp. CCTCC M209061: purification and characterization. PLoS ONE. 2014, 9, (4), e94543.

Bezhan Chankvetadze; Mayuko Saito; Eiji Yashima and Yoshio Okamoto. Enantioseparation of atropisomeric 1,1?-binaphthyl-2,2?-diyl hydrogen phosphate in capillary electrophoresis by using di- and oligosaccharides as chiral selectors: di- and oligosaccharide chiral selectors in capillary electrophoresis. Chirality. 1998, 10, (1-2), 134-139.

For use in the synthesis of chiral ß-lactams, see: J. Chem. Soc., Chem. Commun., 1376 (1988).

Can undergo aldol-type reactions with aldehydes with either syn- or anti-selectivity according to the conditions: Chem. Lett., 1931 (1990).

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H318

Combustible liquid. Causes skin irritation. Causes serious eye damage.

Precautionary Statements: P260u-P201-P280b-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3648161
Harmonized Tariff Code
2918.19
TSCA
No

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