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L14229 2-Bromopropene, 99%, stab.

CAS Number
557-93-7
Synonyms
Isopropenyl bromide

Stock No. Size Price ($) Quantity Availability
L14229-06 5g 42.60
L14229-14 25g 142.00
L14229-22 100g 409.00
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2-Bromopropene, 99%, stab.

MDL
MFCD00000140
EINECS
209-185-4

Chemical Properties

Formula
C3H5Br
Formula Weight
120.98
Melting point
-87°
Boiling Point
47-49°
Flash Point
4°(39°F)
Density
1.362
Refractive Index
1.4430
Storage & Sensitivity
Keep Cold. Light Sensitive.
Solubility
Immiscible with water.

Applications

2-Bromopropene is used as a solvent and as an intermediate for organic synthesis. It is also used as a fumigant. Further, it reacts with nonanal to prepare 2-methyl-undec-1-en-3-ol using chromium(II) chloride as a reagent. It is utilized as a refrigerant used in organic synthesis.

Notes

Light sensitive. Incompatible with strong oxidizing agents and strong bases.

Literature References

Bracco, L. L. B.; Badenes, M. P.; Tucceri, M. E.; Cobos, C. J. Theoretical kinetic study of the unimolecular decomposition of 2-bromopropene. Chem. Phys. Lett. 2014, 608, 386-392.

Vila, C.; Giannerini, M.; Hornillos, V.; Fañanás-Mastral, M.; Feringa, B. L. Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents. Chem. Sci. 2014, 5 (4), 1361-1367.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1731926
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
UC7085000

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