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L14308 Vinylidene chloride, 99%, stab. with 200 ppm 4-methoxyphenol

CAS Number
75-35-4
Synonyms
1,1-Dichloroethylene

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Bulk/Specialty

Vinylidene chloride, 99%, stab. with 200 ppm 4-methoxyphenol

MDL
MFCD00011653
EINECS
200-864-0

Chemical Properties

Formula
C2H2Cl2
Formula Weight
96.94
Melting point
-123°
Boiling Point
30-32°
Flash Point
-25°(-13°F)
Density
1.213
Refractive Index
1.4255
Storage & Sensitivity
Keep Cold. Light Sensitive.
Solubility
Soluble in water (2.5g/L at 20°C).

Applications

Vinylidene chloride is used as pharmaceutical intermediate and in chemical research.

Notes

It is sensitive to light and moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature is 2 - 8°C. Store under inert gas.

Literature References

Frederick M. Lewis.; Frank R. Mayo.; William F. Hulse. Copolymerization. II. The Copolymerization of Acrylonitrile, Methyl Methacrylate, Styrene and Vinylidene Chloride. J. Am. Chem. Soc. 1945, 67 (10), 1701-1705.

Daniel C. Liebler.; F. Peter Guengerich. Olefin oxidation by cytochrome P-450: evidence for group migration in catalytic intermediates formed with vinylidene chloride and trans-1-phenyl-1-butene. Biochemistry. 1983, 22 (24), 5482-5489.

GHS Hazard and Precautionary Statements

Hazard Statements: H224-H302+H332-H319-H351-H373

Extremely flammable liquid and vapour. Harmful if swallowed. Harmful if inhaled. Causes serious eye irritation. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P210-P233-P240-P241-P242-P243-P260-P264b-P270-P271-P280i-P281-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P330-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,9996
Beilstein
1733365
Hazard Class
3
Packing Group
I
Harmonized Tariff Code
2903.29
TSCA
Yes
RTECS
KV9275000

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