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L14728 4'-Chloro-2,2':6',2''-terpyridine, 98%

CAS Number
128143-89-5
Synonyms

Stock No. Size Price ($) Quantity Availability
L14728-MD 250mg 43.70
L14728-03 1g 107.00
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4'-Chloro-2,2':6',2''-terpyridine, 98%

MDL
MFCD00191930

Chemical Properties

Formula
C15H10ClN3
Formula Weight
267.72
Melting point
148-152°
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,µ-bishydroxy-functionalized poly(propylene oxide).

Notes

Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Zhang, G.; Tan, J.; Zhang, Y. Z.; Ta, C.; Sanchez, S.; Cheng, S. Y.; Golen, J. A.; Rheingold, A. L. Syntheses, structures and cytotoxicity of cobalt(II) complexes with 4'-chloro-2,2':6',2?-terpyridine. Inorg. Chim. Acta 2015, 435, 147-152.

Saghatforoush, L. A.; Valencia, L.; Chalabian, F.; Ghammamy, S.; Khaledi, L. Z. Synthesis, crystal structure, and biological activity of 4'-chloro-2,2'?:?6',2?-terpyridine (Cltpy) as tridentate ligand in a Cd(II) complex. J. Coord. Chem. 2011, 64 (19), 3311-3322.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H318-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3613386
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
No

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