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4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,µ-bishydroxy-functionalized poly(propylene oxide).
Zhang, G.; Tan, J.; Zhang, Y. Z.; Ta, C.; Sanchez, S.; Cheng, S. Y.; Golen, J. A.; Rheingold, A. L. Syntheses, structures and cytotoxicity of cobalt(II) complexes with 4'-chloro-2,2':6',2?-terpyridine. Inorg. Chim. Acta 2015, 435, 147-152.
Saghatforoush, L. A.; Valencia, L.; Chalabian, F.; Ghammamy, S.; Khaledi, L. Z. Synthesis, crystal structure, and biological activity of 4'-chloro-2,2'?:?6',2?-terpyridine (Cltpy) as tridentate ligand in a Cd(II) complex. J. Coord. Chem. 2011, 64 (19), 3311-3322.
Hazard Statements: H301-H315-H318-H335
Toxic if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant