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Reducing agent for the preparation of plate-type palladium-zinc oxide catalys, reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents. Catalyst for regioselective reductive opening of benzylidene acetal glycosides and polarity reversal.
Alessandro D'Ulivo; Valeria Loreti; Massimo Onor; Emanuela Pitzalis; Roberto Zamboni. Chemical vapor generation atomic spectrometry using amineboranes and cyanotrihydroborate(III) reagents. Analytical chemistry.2003, 75,(11), 2591-2600.
Andrei A. Sherman et. al. The presence of water improves reductive openings of benzylidene acetals with trimethylaminoborane and aluminum chloride. Carbohydrate Research,.2003, 338(8), 697-703.
Selective reducing agent. Reactivity in carbonyl reductions is promoted by protic or Lewis acids: J. Am. Chem. Soc., 86, 3882 (1964). In the presence of HCl, indoles are reduced to indolines: Synthesis, 508 (1974). For a review of amine boranes, see: Org. Prep. Proced. Int., 16, 335 (1984).
Hazard Statements: H228-H315-H319-H335
Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210-P240-P241-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P374
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Fight fire with normal precautions from a reasonable distance.