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Reactant used for preparation of phosphine-free Suzuki-Miyaura cross-coupling reactions, regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intermolecular aminocarbonylation and annulation, N-arylation using copper acetylacetonate catalys, copper-mediated cyanation and regioselective cyanation of electron-rich benzenes, New linear poly(phenylpyridyl) chains by Suzuki coupling and Oligopyridyl foldamers as mimics of a-helix twist.
Isidro Cobo et. al. Phosphine-free Suzuki-Miyaura cross-coupling in aqueous media enables access to 2-C-aryl-glycosides. Organic Letters.2012, 14,(7), 1728-1731.
Antoine Dieudonné-Vatran et. al. A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation. Organic & Biomolecular Chemistry.,2012,
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.